It might be a bit weird, unless you have some super unique skill set that would fit in with the sorority you were interested in via your friend. That's not to say its impossible, but groups may have have differing requirements on who can volunteer and in what particular capacity as far as non-members go.
I don't know how far the AI path you were on, but for the sake of full disclosure, its something that isn't necessarily a common occurrence, and the process can sometimes take a while, if it even happens for an individual. Please also keep this in mind too if your friend hadn't told you this before alumnae membership and AI are quite different from the collegiate experience.
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