If these locals are anything like NPC groups, then volunteering and your commitment to a particular philanthropy is going to be only one part of the membership selection process.
Above almost everything else, NPC groups (and I assume these locals, as well) look for a well-rounded personality that gets along really well with the women in the chapter. Most social sororities participate in a variety of activities: social, philanthropic, academic, personal development, etc.
OP- you sound like you're putting all your eggs in the service basket. Are these groups PRIMARILY service groups? You also sound like you're overthinking the application and reasons for joining. Practice your conversation, chat with people you know who are in these groups, and read through the pages and pages of advice here.
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I heart Gamma Phi Beta
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