It's hard to say whether American fraternities would be interested in having a chapter abroad, what with the expense of maintaining it from afar, etc. (There are pretty few fraternities in Hawaii and Alaska, for example, because it can get expensive with them being so far away).
I'm quite certain that NPHC groups have European chapters, perhaps initially intended for Americans living overseas?
LYON AZD is correct, Kappa Sigma has roots in Italy.
There are lots of fraternity websites...have a look at them and perhaps email some inquiries.
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