The music should all be on the hard drive, they just don't show up for different users. They are stored in C:\Documents and Settings\<Username.. the admin account you're not using>\My Documents\My Music\Itunes
You can copy the contents of that whole folder to your new My Documents\My Music\Itunes folder.
The main thing that's important is that the computer is authorized to your Itunes account. When you try to listen to one of the songs you copied over, it might tell you that it's not authorized but it will give you the option to authorize it by logging in to Itunes with your aol/apple account username and password, the one you have to put in when you buy songs.
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