If you are open minded to movies that are not quite as new, Primal Fear is a great movie with a twist. The Usual Suspects with "Kaiser Sose" was pretty good too (watch the movie and you'll see what we're getting at).

A terrific old movie is Hush, Hush, Sweet Charlotte with Bette Davis and also the original Psycho in black and white was very SCARY! Much more scary than the remake with Vince Vaughn and Anne Heche. I saw Mission Impossible 2, but was disappointed.