Everything everyone posted is true, especially the part about varying by campus.
But, I would think your "duties" are the same as any other big. Look out for your little. When she needs someone to talk to about her issues, listen and offer advice. If she's on track to do something dumb, intervene. Guide her through the nuances of your school's Greek Life.
Do you know any other guys who are Bigs to the chapter? They'd be a good resource.
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