As an HR professional who just ended a 5 month unemployment period, I have a lot of experience (on both sides) with phone interviews.
Is your phone interview with an HR person? If so, this person is probably only going to qualify you. Be prepared to answer detailed questions about your resume (gaps in employments, why you are looking to leave current job, etc.), salary requirements and some general info about your experience. The questions about experience will probably closely align with the job description or ad, so make sure you spend some time thinking about how your background/qualifications match what they are looking for.
Definately have all of your supporting documentation in front of you: resume, ad/job description, etc. to refer to.
I know a lot of people said dress up for the interview, but this is not really an issue for me. Because I have worked at home in the past, I can do a killer phone screen in my pajamas (and I know because I have!), but if that helps you, go for it.
I've heard other people suggest that you have a small mirror in front of you so you can see what you look like. If you are smiling most likely that will come across in your voice. Speaking of voice, make sure you are upbeat and energetic. Nothing worst that doing your 3rd or 4th screen of the day and the person is monotone. Puts me to sleep and if I zone out on part of your qualifications I am less likely to move you to the next level.
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